Alkyl-metal and aryl-metal bond chemistry in coordinately unsaturated polynuclear metal complexes
نویسندگان
چکیده
منابع مشابه
Alkyl - , Aryl - , and Acyl - metal ( m ) Complexes of Aetioporphyrin I
Reaction of pyridinobromocobalt(llI) aetioporphyrin I with a variety of alkyland aryl-magnesium bromides gives the corresponding alkyland aryl-cobalt(lIl) derivatives. In an alternative synthesis, the cobalt(l) derivative of aetioporphyrin J reacts with alkyl or acyl halides to give the alkylor acyl-cobalt(llI) compounds. The latter approach has also been used for the preparation of hydroxyalky...
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ژورنال
عنوان ژورنال: Proceedings of the National Academy of Sciences
سال: 1981
ISSN: 0027-8424,1091-6490
DOI: 10.1073/pnas.78.3.1318